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. 1999 Aug;38(16):2372-2375.
doi: 10.1002/(sici)1521-3773(19990816)38:16<2372::aid-anie2372>3.0.co;2-h.

The First Efficient Hydroaminomethylation with Ammonia: With Dual Metal Catalysts and Two-Phase Catalysis to Primary Amines

B Zimmermann  1 , J Herwig, M Beller
Affiliations

The First Efficient Hydroaminomethylation with Ammonia: With Dual Metal Catalysts and Two-Phase Catalysis to Primary Amines

B Zimmermann et al. Angew Chem Int Ed Engl. 1999 Aug.

Abstract

Primary and unbranched secondary amines are obtained by the highly selective hydroaminomethylation of olefins with ammonia [Eq. (a)]. The selectivity is readily controlled with a new dual Rh/Ir catalyst in a two-phase system.

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