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. 1999 Oct 18;38(20):3021-3026.
doi: 10.1002/(sici)1521-3773(19991018)38:20<3021::aid-anie3021>3.0.co;2-i.

Heterogeneous Catalysis with Cross-Linked Lyotropic Liquid Crystal Assemblies: Organic Analogues to Zeolites and Mesoporous Sieves

SA Miller  1 , E Kim, DH Gray, DL Gin
Affiliations

Heterogeneous Catalysis with Cross-Linked Lyotropic Liquid Crystal Assemblies: Organic Analogues to Zeolites and Mesoporous Sieves

SA Miller et al. Angew Chem Int Ed Engl. .

Abstract

Organic, nanoporous heterogeneous catalysts based on a carboxylate-containing, amphiphilic mesogen catalyze the Knoevenagel condensation (see schematic representation). These networks maintain their order in solution and can be recycled. Enhanced basicity, excellent site accessibility, and substrate size exclusion are features of these nanostructured systems.

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