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Graphic representation of the rate constants in a linear kinetic scheme. (Top) The…
Figure 1
Graphic representation of the rate constants in a linear kinetic scheme. (Top) The kinetic scheme denoting the kinetic states (S0 − S5) and the rate constants (k1 − k10). (Bottom left-hand axis) The three lines denote rate constant representations using and ff = 1 s−1 (______), 109 s−1 (……), and 6 · 1012 s−1 (- - - -), respectively (for k1 = k10 = 107 s−1, k2 = k9 = 105 s−1, k3 = k8 = 106 s−1, k4 = k7 = 107 s−1, and k5 = k6 = 103 s−1). (Note that for ff = 1 s−1, the peaks are below the wells.) (Bottom, right-hand axis) The free energy profile deduced using (- - - -) and a similar profile deduced using ff = 109 s−1 (……).