The First Cyclodiasteromeric
- PMID: 10602231
- DOI: 10.1002/(sici)1521-3773(19991203)38:23<3528::aid-anie3528>3.3.co;2-e
The First Cyclodiasteromeric
Abstract
A mechanically linked molecule, consisting of an axle and two equivalent wheels, shows an analogous stereochemistry to the classical example tartaric acid. Though the components are not chiral themselves, a (cyclo)diastereomeric species is obtained, the enantiomers (shown schematically) and the meso form of which were completely separated and chiroptically characterized.
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