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. 1999 Oct 21;1(8):1287-90.
doi: 10.1021/ol990964z.

Mechanism and conditions for highly enantioselective epoxidation of alpha,beta-enones using charge-accelerated catalysis by a rigid quaternary ammonium salt

E J Corey  1 , F Y Zhang
Affiliations

Mechanism and conditions for highly enantioselective epoxidation of alpha,beta-enones using charge-accelerated catalysis by a rigid quaternary ammonium salt

E J Corey et al. Org Lett. .

Abstract

[formula: see text] Highly enantioselective (up to 130:1) epoxidation of a variety of alpha,beta-enones to form alpha,beta-epoxy ketones is described along with a rational analysis of the mechanistic basis for this strong absolute stereochemical control by the chiral catalyst 2.

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