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. 2000 Jul 13;2(14):2105-8.
doi: 10.1021/ol006008v.

Platinum-catalyzed diboration using a commercially available catalyst: diboration of aldimines to alpha-aminoboronate esters

G Mann  1 , KD John, RT Baker
Affiliations

Platinum-catalyzed diboration using a commercially available catalyst: diboration of aldimines to alpha-aminoboronate esters

G Mann et al. Org Lett. .

Abstract

Commercially available Pt(cod)Cl(2) catalyzes the diboration of alkenes, alkynes, and aldimines using bis(catecholato)diboron (cod = 1,5-cyclooctadiene). Catalyzed aldimine diboration provides the first direct route to alpha-aminoboronate esters. The diboration product from N-benzylidene-2,6-dimethylaniline is structurally characterized.

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