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. 2000 Sep:56 (Pt 9):1088-9.
doi: 10.1107/s0108270100008787.

A ruthenium(II) complex with p-cymene and (S)-2-(anilinomethyl)pyrrolidine

M Aitali  1 , El Firdoussi L, A Karim, AF Barrero, M Quiros
Affiliations

A ruthenium(II) complex with p-cymene and (S)-2-(anilinomethyl)pyrrolidine

M Aitali et al. Acta Crystallogr C. 2000 Sep.

Abstract

The title compound, [(S)-2-(anilinomethyl)pyrrolidine-N, N']-chloro(eta(6)-para-cymene)ruthenium(II) chloride, [RuCl-(C(10)H(14))(C(11)H(16)N(2))]Cl, has been synthesized by the reaction of [RuCl(2)(p-cymene)](2) (p-cymene is para-isopropyltoluene) with (S)-2-(anilinomethyl)pyrrolidine in triethylamine/2-propanol. The Ru atom is in a pseudo-tetrahedral environment coordinated by a chloride ligand, the aromatic hydrocarbon is linked in a eta(6) manner and the amine is linked via its two N atoms. The chloride anion is involved in hydrogen bonding with the diamine moieties through N-H.Cl interactions, with N.Cl distances of 3.273 (4) and 3.352 (4) A.

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