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. 2000 Aug 24;2(17):2707-9.
doi: 10.1021/ol006286u.

Aluminum- and boron-mediated c-glycoside synthesis from 1,2-anhydroglycosides

J D Rainier  1 , J M Cox
Affiliations

Aluminum- and boron-mediated c-glycoside synthesis from 1,2-anhydroglycosides

J D Rainier et al. Org Lett. .

Abstract

[reaction: see text]This letter describes a single flask strategy to the synthesis of alpha-C-glycosides from glycals. This protocol couples a glycal epoxidation reaction with a C-2 alkoxy-directed carbon-carbon bond-forming reaction.

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