doi: 10.1016/s0162-0134(00)00077-5.
First syntheses and X-ray structures of a meso-alkyl-substituted corrole and its Ga(III) complex
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- PMID: 11001094
- DOI: 10.1016/s0162-0134(00)00077-5
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First syntheses and X-ray structures of a meso-alkyl-substituted corrole and its Ga(III) complex
J Inorg Biochem.
.
Abstract
The solvent-free condensation of heptafluorobutanal and pyrrole leads to the corresponding meso-alkyl-substituted corrole, which was metallated by gallium chloride to provide the first first-row non-transition-metal corrole. Both the ligand and the complex were characterized by X-ray crystallography.
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