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. 2000 Jul 1;80(3-4):235-8.
doi: 10.1016/s0162-0134(00)00077-5.

First syntheses and X-ray structures of a meso-alkyl-substituted corrole and its Ga(III) complex

L Simkhovich  1 , I Goldberg, Z Gross
Affiliations

First syntheses and X-ray structures of a meso-alkyl-substituted corrole and its Ga(III) complex

L Simkhovich et al. J Inorg Biochem. .

Abstract

The solvent-free condensation of heptafluorobutanal and pyrrole leads to the corresponding meso-alkyl-substituted corrole, which was metallated by gallium chloride to provide the first first-row non-transition-metal corrole. Both the ligand and the complex were characterized by X-ray crystallography.

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