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. 2000 Nov 3;65(22):7272-6.
doi: 10.1021/jo001044t.

The synthesis and chemoselective reactivity of 3-aminocyclopentadienones

JD Rainier  1 , JE Imbriglio
Affiliations

The synthesis and chemoselective reactivity of 3-aminocyclopentadienones

JD Rainier et al. J Org Chem. .

Abstract

Iron and cobalt complexes of 3-aminocyclopentadienones have been synthesized from the [2 + 2 + 1] cycloadditions of nitrogen acetylenes and pendant alkynes. Following decomplexation, the resulting 3-aminocyclopentadienones have been subjected to chemo- and regioselective cycloadditions with dienophiles and heterodienes.

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