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. 2000 Nov 30;2(24):3877-9.
doi: 10.1021/ol006618v.

Palladium-catalyzed additions of silyl-element bonds to bicyclopropylidene-A new access to bicyclopropyl and functionally substituted cyclopropylidenepropane derivatives

T Pohlmann  1 , de Meijere A
Affiliations

Palladium-catalyzed additions of silyl-element bonds to bicyclopropylidene-A new access to bicyclopropyl and functionally substituted cyclopropylidenepropane derivatives

T Pohlmann et al. Org Lett. .

Abstract

Palladium-catalyzed additions of disilanes, silylboranes, silylstannanes, and silyl cyanides across the double bond of bicyclopropylidene proceed with remarkable ease by two modes yielding either bicyclopropyl or cyclopropylidenepropane derivatives.

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