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. 2000 Dec 14;2(25):3975-7.
doi: 10.1021/ol0063914.

Enantioselective allyltitanation. Efficient synthesis of the C1-C14 polyol subunit of amphotericin B

S BouzBouz  1 , J Cossy
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Enantioselective allyltitanation. Efficient synthesis of the C1-C14 polyol subunit of amphotericin B

S BouzBouz et al. Org Lett. .

Abstract

[structure] An efficient synthesis of the C(1)-C(14) fragment of amphotericin B is described. This synthesis is based on the formation of syn-1,3-diols from enantioselective allyltitanation of unprotected beta-hydroxyaldehydes.

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