Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2000 Dec:56 (Pt 12):1433-4.
doi: 10.1107/s010827010001310x.

Solvent-free

O Crespo  1 , MC Gimeno, PG Jones, A Laguna
Affiliations

Solvent-free

O Crespo et al. Acta Crystallogr C. 2000 Dec.

Abstract

The title compound, [Au(2)Cl(2)Fe(C(17)H(14)P)(2)], (I), contains the expected linear gold centres. The ferrocene moiety acts as a P, P'-bridging ligand, wherein the Fe atom lies on an inversion centre. The P-Au-Cl angle is 177.56 (8) degrees and bond distances Au-P and Au-Cl are 2.2261 (18) and 2.2781 (18) A, respectively. The structure is almost identical to that of the metal complex in (I).2CH(2)Cl(2) [Canales, Gimeno, Jones, Laguna & Sarroca (1997). Inorg. Chem. 36, 5206-5211], but differs considerably from that in 3(I).2CHCl(3) [Hill, Girard, McCabe, Johnson, Stupik, Zhang, Reiff & Eggleston (1989). Inorg. Chem. 28, 3529-3533], in that in the latter, the two independent molecules are linked by a short Au.Au contact.

PubMed Disclaimer