Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2001 Jan;57(Pt 1):4-6.
doi: 10.1107/s0108270100013093.

A saccharinate-iron(II) complex with a free saccharin molecule present, [Fe(phen)3]sac2.sacH.6H2O

R M Deng  1 , S Simon, K B Dillon, A E Goeta
Affiliations

A saccharinate-iron(II) complex with a free saccharin molecule present, [Fe(phen)3]sac2.sacH.6H2O

R M Deng et al. Acta Crystallogr C. 2001 Jan.

Abstract

The crystal structure of the title compound, tris(1,10-phenanthroline-N,N')iron(II) bis[1,2-benzisothiazol-3(2H)-onate 1,1-dioxide] 1,2-benzisothiazol-3(2H)-one 1,1-dioxide hexahydrate, [Fe(C12H8N2)3](C7H4NO3S)2.C7H5NO3S.6H2O, at 120 K consists of slightly distorted octahedral [Fe(phen)3]2+ cations (phen is 1,10-phenanthroline), two saccharinate anions and a free saccharin molecule, as well as six waters of crystallization. The compound has been confirmed as diamagnetic low-spin iron(II) by magnetic measurements. There is extensive hydrogen bonding leading to a three-dimensional network.

PubMed Disclaimer

LinkOut - more resources