doi: 10.1016/s0031-9422(00)00403-9.
Biotransformation of diterpenes and diterpene derivatives by Beauveria bassiana ATCC 7159
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- PMID: 11220282
- DOI: 10.1016/s0031-9422(00)00403-9
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Biotransformation of diterpenes and diterpene derivatives by Beauveria bassiana ATCC 7159
Phytochemistry.
2001 Jan.
Abstract
The biohydroxylation of stemodin and stemodinone by Beauveria bassiana ATCC 7159 gave exclusively 2alpha,13,18-trihydroxystemodane and 13,18-dihydroxystemodan-2-one respectively. Stemarin was converted to the novel 1beta,13,19-trihydroxystemarane and 13-hydroxystemarane-19-carboxylic acid. The synthesis and biotransformation of various derivatives of stemodin have also been studied.
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