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. 2001 Jan;56(2):141-51.
doi: 10.1016/s0031-9422(00)00403-9.

Biotransformation of diterpenes and diterpene derivatives by Beauveria bassiana ATCC 7159

G O Buchanan  1 , P B Reese
Affiliations

Biotransformation of diterpenes and diterpene derivatives by Beauveria bassiana ATCC 7159

G O Buchanan et al. Phytochemistry. 2001 Jan.

Abstract

The biohydroxylation of stemodin and stemodinone by Beauveria bassiana ATCC 7159 gave exclusively 2alpha,13,18-trihydroxystemodane and 13,18-dihydroxystemodan-2-one respectively. Stemarin was converted to the novel 1beta,13,19-trihydroxystemarane and 13-hydroxystemarane-19-carboxylic acid. The synthesis and biotransformation of various derivatives of stemodin have also been studied.

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