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. 2001 Mar 8;3(5):731-3.
doi: 10.1021/ol007047+.

Stereoselective transformations on D-glucose-derived eight-membered ring carbocycles

P A van Hooft  1 , R E Litjens, G A van der Marel, C A van Boeckel, J H van Boom
Affiliations

Stereoselective transformations on D-glucose-derived eight-membered ring carbocycles

P A van Hooft et al. Org Lett. .

Abstract

[structure: see text]. The cyclooctenol derivative 1 can be transformed into the nine-membered ring lactone 3, as well as the amino-containing carbocycles 4 and 5. The corresponding ketone 2 gives access to the conformationally locked azasugar 6.

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