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. 2001 Apr;57(Pt 4):366-7.
doi: 10.1107/s0108270100020515.

(N-[2-(eta[5]cyclopentadienyl)ethyl]-4-toluenesulfonamido-N,O)(tetrahydrofuran-O)bis(trifluoromethanesulfonato-O)titanium(II)

C Lensink  1 , G J Gainsford, N I Baxter
Affiliations

(N-[2-(eta[5]cyclopentadienyl)ethyl]-4-toluenesulfonamido-N,O)(tetrahydrofuran-O)bis(trifluoromethanesulfonato-O)titanium(II)

C Lensink et al. Acta Crystallogr C. 2001 Apr.

Abstract

The title compound, [Ti(CF(3)O(3)S)(2)(C(14)H(15)NO(2)S)(C(4)H(8)O)], contains a unique ligand system in which the Ti ion is bound to the N and O atoms of a 2-p-toluenesulfonamide ligand, which is linked by an ethyl group to a coordinated cyclopentadiene moiety. The distorted octahedral geometry about the Ti ion is completed by two trifluoromethanesulfonate ligands and a tetrahydrofuran molecule. Comparison with related compounds shows that both the Ti-N and Ti-O bonds of the sulfonamide, although longer than normal values, indicate significant bonding interactions.

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