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. 2001 May 18;66(10):3423-6.
doi: 10.1021/jo001737+.

Synthesis of (-)-delobanone

D F Taber  1 , G Bui, B Chen
Affiliations

Synthesis of (-)-delobanone

D F Taber et al. J Org Chem. .

Abstract

On irradiation in the presence of Fe(CO)(5) under a CO atmosphere, the alkenyl cyclopropane 2 underwent smooth ring expansion to give the sesquiterpene (-)-delobabone 3. The alkenyl cyclopropane 2 was prepared from the enantiomerically enriched epoxide 1.

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