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. 2001 May 31;3(11):1721-4.
doi: 10.1021/ol0159165.

A rhodium carbene cyclization-cycloaddition cascade strategy toward the pseudolaric acids

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A rhodium carbene cyclization-cycloaddition cascade strategy toward the pseudolaric acids

P Chiu et al. Org Lett. .

Abstract

A rhodium carbene intramolecular cyclization-cycloaddition cascade was employed as the key reaction in the synthesis of the nucleus of the cytotoxic diterpenoids pseudolaric acids A and B.

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