Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2001 Jul 26;3(15):2357-60.
doi: 10.1021/ol016160c.

Radical transfer hydrosilylation/cyclization using silylated cyclohexadienes

S Amrein  1 , A Timmermann, A Studer
Affiliations

Radical transfer hydrosilylation/cyclization using silylated cyclohexadienes

S Amrein et al. Org Lett. .

Abstract

[reaction: see text] A new method for mild metal-free hydrosilylation is described. Silylated cyclohexadienes are used as radical transfer hydrosilylating reagents for various double and triple bonds. A trialkylsilane is transferred from a cyclohexadiene moiety to an alkene. The hydrosilylation can be combined with a C-C bond formation as shown for the preparation of silylated cycloalkanes from the corresponding dienes.

PubMed Disclaimer

LinkOut - more resources