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. 2001 Aug 9;3(16):2455-6.
doi: 10.1021/ol016108g.

The first 2,2-dialkoxythiirane

M Dawid  1 , G Mlostoñ, J Warkentin
Affiliations

The first 2,2-dialkoxythiirane

M Dawid et al. Org Lett. .

Abstract

[reaction: see text] Thermolysis of 1 at 110 degrees C in benzene containing adamantanethione leads to thiirane 2 in 92% yield, as an isolable, stable solid. Compound 2 is the first example of the hitherto unknown 2,2-dialkoxythiiranes. It shows some reactions characteristic of thiiranes.

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