Polychlorinated biphenyls and other organic chemical residues in fish from major watersheds of the United States, 1976

Abstract

Composite samples of fish were collected from major United States watersheds in 1976 and analyzed for PCBs and related organic chemicals. PCBs were found in 93 percent of the fish samples; 53 percent of the samples contained more than 5 ppm PCBs, whole fish basis, which is the current tolerance level set by the Food and Drug Administration, U.S. Department of Health, Education and Welfare. Only 14 percent of the samples contained less than the proposed action level of 2 ppm PCBs. PCB concentrations ranged from less than 0.3 ppm to 140 ppm in the composite samples. sigma DDT concentrations ranged from less than 0.05 ppm to 4.53 ppm. Hexachlorobenzene was identified in 19 percent of the samples, and chlordane components were identified in 36 percent of the samples. Chemicals identified by gas chromatography/mass spectrometry but not quantified include chlorinated benzenes, styrenes, anisoles, phenols, anilines, propanes, and butadienes, as well as mixtures of petroleum hydrocarbons.