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. 2001 Dec 13;3(25):4087-9.
doi: 10.1021/ol016847x.

N-Cyclopropylimine-1-pyrroline rearrangement. A novel photochemical reaction

P J Campos  1 , A Soldevilla, D Sampedro, M A Rodríguez
Affiliations

N-Cyclopropylimine-1-pyrroline rearrangement. A novel photochemical reaction

P J Campos et al. Org Lett. .

Abstract

[reaction: see text] A novel aza-(vinylcyclopropane-cyclopentene) photochemical rearrangement is reported. 1-Pyrrolines are easily synthesized in good yields from N-cyclopropylimines. Hydrogen, alkyl, and aryl groups can be placed anywhere within the system, and the reaction proceeds regiospecifically.

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