Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2002 Jan 30;124(4):518-9.
doi: 10.1021/ja0113091.

Reactions of iodinated vinylidene complexes generated from 1-iodo-1-alkynes and W(CO)5(thf)

Tomoya Miura  1 , Nobuharu Iwasawa
Affiliations

Reactions of iodinated vinylidene complexes generated from 1-iodo-1-alkynes and W(CO)5(thf)

Tomoya Miura et al. J Am Chem Soc. .

Abstract

We have succeeded in generating iodinated tungsten vinylidene complexes from 1-iodo-1-alkynes and W(CO)5(thf), and have employed these complexes for two types of synthetically useful reactions, that is, 6pi-electrocyclization for o-(iodoethynyl)styrenes and endo-selective cyclization for omega-iodoacetylenic silyl enol ethers.

PubMed Disclaimer

LinkOut - more resources