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. 2002 Mar;58(Pt 3):m160-1.
doi: 10.1107/s010827010200032x. Epub 2002 Feb 13.

Chlorobis(triphenylphosphine)nickel(I)

Nicholas C Norman  1 , A Guy Orpen, Michael J Quayle, George R Whittell
Affiliations

Chlorobis(triphenylphosphine)nickel(I)

Nicholas C Norman et al. Acta Crystallogr C. 2002 Mar.

Abstract

Crystals of the title compound, [NiCl(C(18)H(15)P)(2)], contain one molecule per asymmetric unit with no short intermolecular interactions. This is noteworthy since previous studies have reported that the formally 15-electron species oligomerizes in the solid state. The nickel(I) centre has a distorted trigonal-planar coordination geometry, the origin of which is suggested to be electronic in nature.

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