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. 2002 Mar;58(Pt 3):m186-7.
doi: 10.1107/s0108270101020601. Epub 2002 Feb 20.

Tris(1-ethyl-3-methylimidazolium) hexachlorolanthanate

Kazuhiko Matsumoto  1 , Tetsuya Tsuda, Toshiyuki Nohira, Rika Hagiwara, Yasuhiko Ito, Osamu Tamada
Affiliations

Tris(1-ethyl-3-methylimidazolium) hexachlorolanthanate

Kazuhiko Matsumoto et al. Acta Crystallogr C. 2002 Mar.

Abstract

In the title complex, (C(6)H(11)N(2))(3)[LaCl(6)], centrosymmetric octahedral hexachlorolanthanate anions are located at the corners and face-centers of the monoclinic unit cell. The ring H atoms of the cations interact with the Cl atoms of the anions via hydrogen bonding, and bifurcation of the hydrogen bonding is observed. Cation-cation interactions via hydrogen bonding between the ring H atoms and pi-electrons of aromatic rings are also observed as in other imidazolium salts.

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