Two thiourea-containing gold(I) complexes

Abstract

The crystal structures of two salts of bis(thiourea)gold(I) complexes, namely bis(thiourea-kappaS)gold(I) chloride, [Au(CH(4)N(2)S)(2)]Cl, (I), and bis[bis(thiourea-kappaS)gold(I)] sulfate, [Au(CH(4)N(2)S)(2)](2)SO(4), (II), have been determined. The chloride salt, (I), is isomorphous with the corresponding bromide salt, although there are differences in the bonding. The Au(I) ion is located on an inversion centre and coordinated by two symmetry-related thiourea ligands through the lone pairs on their S atoms [Au-S 2.278 (2) A and Au-S-C 105.3 (2) degrees ]. The sulfate salt, (II), crystallizes with four independent [Au(CH(4)N(2)S)(2)]+ cations per asymmetric unit, all with nearly linear S-Au-S bonding. The cations in (II) have similar conformations to that found for (I). The Au-S distances range from 2.276 (3) to 2.287 (3) A and the Au-S-C angles from 173.5 (1) to 177.7 (1) degrees. These data are relevant in interpreting different electrochemical processes where gold-thiourea species are formed.