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. 2002 Apr 2;8(7):1637-40.
doi: 10.1002/1521-3765(20020402)8:7<1637::aid-chem1637>3.0.co;2-7.

Synthesis and reactivity of an alpha-stannyl beta-silyl enamide

Laurianne Timbart  1 , Jean-Christophe Cintrat
Affiliations

Synthesis and reactivity of an alpha-stannyl beta-silyl enamide

Laurianne Timbart et al. Chemistry. .

Abstract

We describe here an unprecedented approach to the synthesis of stereodefined 1,2-bis-substituted enamides. Starting from bis-metallated enamides, a palladium-copper coupling reaction allows the introduction of various groups at C1, whilst iododesilylation affords a new entry for the functionalization at C2.

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