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. 2002 May;58(Pt 5):m316-8.
doi: 10.1107/s0108270102006303. Epub 2002 Apr 30.

(eta3-Allyl-2kappa3C)(chloro-1kappaCl)(micro-N,N'-diethyldithioxamidato-1:2kappa4S,S':N,N')[diphenyl(2-pyridyl)phosphine-1kappaP]palladium(II)platinum(II) chloroform solvate

Giuseppe Bruno  1 , Santo Lanza, Francesco Nicoló, Giuseppe Tresoldi, Giuseppe Rosace
Affiliations

(eta3-Allyl-2kappa3C)(chloro-1kappaCl)(micro-N,N'-diethyldithioxamidato-1:2kappa4S,S':N,N')[diphenyl(2-pyridyl)phosphine-1kappaP]palladium(II)platinum(II) chloroform solvate

Giuseppe Bruno et al. Acta Crystallogr C. 2002 May.

Abstract

The title compound, [PdPtCl(C(3)H(5))(C(6)H(10)N(2)S(2))(C(17)H(14)NP)].CHCl(3), was obtained by deprotonation of the initial platinum(II) complex of the dithioxamide and subsequent reaction with [Pd(eta(3)-C(3)H(5))(micro-Cl)](2). Both metal atoms exhibit a square-planar coordination geometry, with the two planes forming a dihedral angle of 21.7 (2) degrees. The dithioxamide bis-chelating bridge is flat.

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