doi: 10.1021/ja026094p.
The catalytic asymmetric Mannich-type reactions in aqueous media
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- PMID: 12010028
- DOI: 10.1021/ja026094p
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The catalytic asymmetric Mannich-type reactions in aqueous media
J Am Chem Soc.
.
Abstract
The catalytic, diastereo- and enantioselective Mannich-type reaction of a hydrazono ester with silyl enol ethers in aqueous media has been successfully achieved with ZnF(2), a chiral diamine ligand, and trifluoromethanesulfonic acid.
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