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. 2002 May 22;124(20):5640-1.
doi: 10.1021/ja026094p.

The catalytic asymmetric Mannich-type reactions in aqueous media

Shū Kobayashi  1 , Tomoaki Hamada, Kei Manabe
Affiliations

The catalytic asymmetric Mannich-type reactions in aqueous media

Shū Kobayashi et al. J Am Chem Soc. .

Abstract

The catalytic, diastereo- and enantioselective Mannich-type reaction of a hydrazono ester with silyl enol ethers in aqueous media has been successfully achieved with ZnF(2), a chiral diamine ligand, and trifluoromethanesulfonic acid.

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