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. 2002 May 22;124(20):5656-7.
doi: 10.1021/ja0261325.

Direct catalytic asymmetric alpha-amination of aldehydes

Benjamin List  1
Affiliations

Direct catalytic asymmetric alpha-amination of aldehydes

Benjamin List. J Am Chem Soc. .

Abstract

The first direct catalytic asymmetric alpha-amination of aldehydes is described herein. alpha-Unbranched aldehydes react in this novel proline-catalyzed reaction with dialkyl azodicarboxylates to give alpha-amino aldehydes in excellent yields and enantioselectivities.

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