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. 2002 Jun;58(Pt 6):i74-5.
doi: 10.1107/s0108270102006741. Epub 2002 May 11.

Dilithium barium diphosphate

Nezha Dridi  1 , E Arbib, Ali Boukhari, Elizabeth M Holt
Affiliations

Dilithium barium diphosphate

Nezha Dridi et al. Acta Crystallogr C. 2002 Jun.

Abstract

The crystal structure of the novel title diphosphate, Li(2)BaP(2)O(7), exists with a three-dimensional lattice composed of BaO(9) polyhedra linked to corner- and edge-sharing P(2)O(7) diphosphate groups, forming layers parallel to the (010) plane, the layers being linked by P[bond]O[bond]Ba bridges. Tunnels thus created between the layers are occupied by Li(+) cations, two of which lie on twofold axes.

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