doi: 10.1039/b111057h.
Nitrones are suitable ligands for heme models: X-ray crystal structure of the first metalloporphyrin nitrone complex
Affiliations
- PMID: 12120084
- DOI: 10.1039/b111057h
Item in Clipboard
Nitrones are suitable ligands for heme models: X-ray crystal structure of the first metalloporphyrin nitrone complex
Chem Commun (Camb).
.
Abstract
The metalloporphyrin nitrone complexes [M(oep)-(CO)(DMPO)] (M = Ru, Os; oep = octaethylporphyrinato dianion; DMPO = 5,5-dimethyl-1-pyrroline N-oxide) have been prepared: the crystal structure of the Ru complex reveals a sole eta 1-O binding mode of the nitrone ligand to the metal center.
Similar articles
-
Nuclear resonance vibrational spectroscopy applied to [Fe(OEP)(NO)]: the vibrational assignments of five-coordinate ferrous heme-nitrosyls and implications for electronic structure.Inorg Chem. 2010 May 3;49(9):4133-48. doi: 10.1021/ic902181e. Inorg Chem. 2010. PMID: 20345089 Free PMC article.
-
Unexpected nitrosyl-group bending in six-coordinate [M(NO)](6) sigma-bonded aryl(iron) and -(ruthenium) porphyrins.J Am Chem Soc. 2001 Jul 4;123(26):6314-26. doi: 10.1021/ja010276m. J Am Chem Soc. 2001. PMID: 11427056
-
Synthesis, characterization, solid-state molecular structures, and deprotonation reactions of cationic alcohol complexes of osmium nitrosyl porphyrins.Inorg Chem. 2001 Jan 1;40(1):125-33. doi: 10.1021/ic0007512. Inorg Chem. 2001. PMID: 11195370
-
The metal complexes of N-confused porphyrin as heme model compounds.J Inorg Biochem. 2006 Apr;100(4):869-80. doi: 10.1016/j.jinorgbio.2006.01.016. Epub 2006 Feb 28. J Inorg Biochem. 2006. PMID: 16510190 Review.
-
Using anti-5,5-dimethyl-1-pyrroline N-oxide (anti-DMPO) to detect protein radicals in time and space with immuno-spin trapping.Free Radic Biol Med. 2004 May 15;36(10):1214-23. doi: 10.1016/j.freeradbiomed.2004.02.077. Free Radic Biol Med. 2004. PMID: 15110386 Review.
Publication types
MeSH terms
Substances
Grants and funding
LinkOut - more resources
Full Text Sources
Research Materials
Miscellaneous
