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. 2002 Feb 7:(3):210-1.
doi: 10.1039/b109987f.

Immobilized alpha-diazophosphonoacetate as a versatile key precursor for palladium catalyzed indole synthesis on a polymer support

Kazuo Yamazaki  1 , Yoshinori Kondo
Affiliations

Immobilized alpha-diazophosphonoacetate as a versatile key precursor for palladium catalyzed indole synthesis on a polymer support

Kazuo Yamazaki et al. Chem Commun (Camb). .

Abstract

Rh(II)-catalyzed N-H insertion reaction of immobilized alpha-diazophosphonoacetate with 2-haloanilines followed by Horner-Emmons reaction gave immobilized enaminoesters, which were efficiently cyclized to indoles via intramolecular palladium catalyzed reaction on a polymer support.

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