The "diindene" ArInInAr (Ar = C(6)H(3)-2,6-Dipp(2), Dipp = C(6)H(3)-2,6-Pr(i)(2)). Dimeric versus monomeric in(I) aryls: para-substituent effects in terphenyl ligands
- PMID: 12121089
- DOI: 10.1021/ja026285s
The "diindene" ArInInAr (Ar = C(6)H(3)-2,6-Dipp(2), Dipp = C(6)H(3)-2,6-Pr(i)(2)). Dimeric versus monomeric in(I) aryls: para-substituent effects in terphenyl ligands
Abstract
The synthesis and structure of a "diindene" with significant metal-metal bonding are described. It has an In-In distance of 2.9786(5) A, an In-In-C angle of 121.23(6) degrees , and an In-In bond order that is probably less than unity.
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