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. 2002 Jul 26;67(15):5117-23.
doi: 10.1021/jo0160221.

Cyclobutenbriarein A, the first diterpene with a tricyclo[8.4.0.0(3,6)]tetradec-4-ene ring system isolated from the Gorgonian Briareum asbestinum

Noemí González  1 , Jaime Rodríguez, Russell G Kerr, Carlos Jiménez
Affiliations

Cyclobutenbriarein A, the first diterpene with a tricyclo[8.4.0.0(3,6)]tetradec-4-ene ring system isolated from the Gorgonian Briareum asbestinum

Noemí González et al. J Org Chem. .

Erratum in

  • J Org Chem. 2003 Dec 12;68(25):9874

Abstract

Cyclobutenbriarein A (2), a novel class of C20-rearranged diterpene briarane possessing an unprecedented tricyclo[8.4.0.0(3,6)]tetradec-4-ene ring system was isolated, along with five new briarane diterpenoids (1 and 3-6), from the organic extracts of the Bahamian gorgonian Briareum asbestinum. The structures of these secondary metabolites were established on the basis of extensive NMR studies and accurate mass measurements (HRFABMS).

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