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. 2002 Aug 7;124(31):9046-7.
doi: 10.1021/ja026896k.

Excited-state proton transfer in chiral environments. 1. Chiral solvents

Kyril M Solntsev  1 , Laren M Tolbert, Boiko Cohen, Dan Huppert, Yoshihito Hayashi, Yuri Feldman
Affiliations

Excited-state proton transfer in chiral environments. 1. Chiral solvents

Kyril M Solntsev et al. J Am Chem Soc. .

Abstract

Excited-state proton transfer from the "super" photoacid 5,8-dicyano-2-naphthol to 2-butanol is faster in the enantiopure solvent than in its racemic form. The difference observed is discussed in terms of long-range order in homo- and heterodimers of 2-butanol.

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