doi: 10.1021/ja026896k.
Excited-state proton transfer in chiral environments. 1. Chiral solvents
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- PMID: 12148997
- DOI: 10.1021/ja026896k
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Excited-state proton transfer in chiral environments. 1. Chiral solvents
J Am Chem Soc.
.
Abstract
Excited-state proton transfer from the "super" photoacid 5,8-dicyano-2-naphthol to 2-butanol is faster in the enantiopure solvent than in its racemic form. The difference observed is discussed in terms of long-range order in homo- and heterodimers of 2-butanol.
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