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. 2002 Aug 7;124(31):9052-3.
doi: 10.1021/ja026630d.

C1-c5 photochemical cyclization of enediynes

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C1-c5 photochemical cyclization of enediynes

Igor V Alabugin et al. J Am Chem Soc. .

Abstract

This study reports a new photochemical cyclization of tetrafluoropyridinyl (TFP)-substituted enediynes that is accompanied with four formal hydrogen-atom abstractions from organic substrates and is mechanistically different from the Bergman cyclization.

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