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. 2002 Aug 7:(15):1566-7.
doi: 10.1039/b203550b.

A sigma 4, lambda 5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic esters

Marjolaine Doux  1 , Nicolas Mézailles, Mohand Melaimi, Louis Ricard, Pascal Le Floch
Affiliations

A sigma 4, lambda 5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic esters

Marjolaine Doux et al. Chem Commun (Camb). .

Abstract

A palladium(II) complex of a S-P-S pincer ligand featuring a metallated ylidic P-atom efficiently catalyzes the coupling between pinacolborane and various iodoaryls to yield the corresponding arylboronic esters (TON between 5100 and 76,500).

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