doi: 10.1021/ol026613t.
Biaryl synthesis from two different aryl halides with tri(2-furyl)germane
Affiliations
- PMID: 12201743
- DOI: 10.1021/ol026613t
Item in Clipboard
Biaryl synthesis from two different aryl halides with tri(2-furyl)germane
Org Lett.
.
Abstract
[reaction: see text] The coupling reaction of germanium compounds with aryl halides has been developed. The Pd(0)-catalyzed reaction of aryl halides with tri(2-furyl)germane provides aryltri(2-furyl)germanes in good yield. The cross-coupling reaction of aryltri(2-furyl)germanes with aryl halides is achieved. This allows facile synthesis of unsymmetrical biaryls from two different aryl halides.
Similar articles
-
A Pd-catalyzed, boron ester-mediated, reductive cross-coupling of two aryl halides to synthesize tricyclic biaryls.Org Biomol Chem. 2017 Jul 21;15(27):5790-5796. doi: 10.1039/c7ob01237c. Epub 2017 Jun 29. Org Biomol Chem. 2017. PMID: 28660938
-
Highly selective biaryl cross-coupling reactions between aryl halides and aryl Grignard reagents: a new catalyst combination of N-heterocyclic carbenes and iron, cobalt, and nickel fluorides.J Am Chem Soc. 2009 Aug 26;131(33):11949-63. doi: 10.1021/ja9039289. J Am Chem Soc. 2009. PMID: 19639999
-
Biaryl synthesis via Pd-catalyzed decarboxylative coupling of aromatic carboxylates with aryl halides.J Am Chem Soc. 2007 Apr 18;129(15):4824-33. doi: 10.1021/ja068993+. Epub 2007 Mar 22. J Am Chem Soc. 2007. PMID: 17375927
-
Palladium-phosphinous acid-catalyzed cross-coupling of aryl and acyl halides with aryl-, alkyl-, and vinylzinc reagents.J Org Chem. 2008 Oct 3;73(19):7638-50. doi: 10.1021/jo801445y. Epub 2008 Sep 4. J Org Chem. 2008. PMID: 18767805
-
Orthogonal Nanoparticle Catalysis with Organogermanes.Angew Chem Int Ed Engl. 2019 Dec 2;58(49):17788-17795. doi: 10.1002/anie.201910060. Epub 2019 Oct 23. Angew Chem Int Ed Engl. 2019. PMID: 31562670 Free PMC article. Review.
Cited by
-
Non-transition Metal-Mediated Diverse Aryl-Heteroatom Bond Formation of Arylammonium Salts.iScience. 2019 May 31;15:307-315. doi: 10.1016/j.isci.2019.04.038. Epub 2019 May 3. iScience. 2019. PMID: 31102996 Free PMC article.
-
Co-catalyzed arylation of aldehydes and aryltrimethylgermanes.RSC Adv. 2023 Mar 10;13(12):8043-8048. doi: 10.1039/d3ra00836c. eCollection 2023 Mar 8. RSC Adv. 2023. PMID: 36909747 Free PMC article.
-
Synthesis, Structure, Thermal Behavior and cis/trans Isomerization of 2,2'-(EMe₃)₂ (E = C, Si, Ge, Sn) Substituted Azobenzenes.Molecules. 2019 Jan 15;24(2):303. doi: 10.3390/molecules24020303. Molecules. 2019. PMID: 30650637 Free PMC article.
-
Modular and Selective Arylation of Aryl Germanes (C-GeEt3 ) over C-Bpin, C-SiR3 and Halogens Enabled by Light-Activated Gold Catalysis.Angew Chem Int Ed Engl. 2020 Sep 1;59(36):15543-15548. doi: 10.1002/anie.202005066. Epub 2020 Jun 12. Angew Chem Int Ed Engl. 2020. PMID: 32392397 Free PMC article.
-
Vinyl Tris(trimethylsilyl)silanes: Substrates for Hiyama Coupling.Tetrahedron. 2008 May 26;64(22):5322-5327. doi: 10.1016/j.tet.2008.03.024. Tetrahedron. 2008. PMID: 19478830 Free PMC article.
LinkOut - more resources
Full Text Sources
