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. 2002 Sep 5;4(18):3165-7.
doi: 10.1021/ol026613t.

Biaryl synthesis from two different aryl halides with tri(2-furyl)germane

Tomoaki Nakamura  1 , Hidenori Kinoshita, Hiroshi Shinokubo, Koichiro Oshima
Affiliations

Biaryl synthesis from two different aryl halides with tri(2-furyl)germane

Tomoaki Nakamura et al. Org Lett. .

Abstract

[reaction: see text] The coupling reaction of germanium compounds with aryl halides has been developed. The Pd(0)-catalyzed reaction of aryl halides with tri(2-furyl)germane provides aryltri(2-furyl)germanes in good yield. The cross-coupling reaction of aryltri(2-furyl)germanes with aryl halides is achieved. This allows facile synthesis of unsymmetrical biaryls from two different aryl halides.

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