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. 2002 Oct 9;124(40):11870-1.
doi: 10.1021/ja027774v.

A readily-accessible (+)-sparteine surrogate

Michael J Dearden  1 , Catherine R Firkin, Jean-Paul R Hermet, Peter O'Brien
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A readily-accessible (+)-sparteine surrogate

Michael J Dearden et al. J Am Chem Soc. .

Abstract

A "(+)-sparteine-like" chiral diamine, readily synthesized in three steps from (-)-cytisine, has been evaluated in four different asymmetric transformations; in each case, selectivity in an enantiocomplementary fashion to (-)-sparteine was observed.

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