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. 2002 Oct;58(Pt 10):o608-9.
doi: 10.1107/s0108270102016025. Epub 2002 Sep 30.

N,N'-dibenzyldithiooxamide

Giuseppe Bruno  1 , Santo Lanza, Francesco Nicoló, Giuseppe Tresoldi, Giuseppe Rosace
Affiliations

N,N'-dibenzyldithiooxamide

Giuseppe Bruno et al. Acta Crystallogr C. 2002 Oct.

Abstract

The title compound, alternatively known as N,N'-dibenzylethanedithioamide, C(16)H(16)N(2)S(2), lies about an inversion centre and contains a planar trans-dithiooxamide fragment characterized by a strong intramolecular hydrogen bond between the S atom and the adjacent amide H atom in the solid state, with an S...N distance of 2.926 (1) A. The aryl substituent is oriented orthogonal to the mean plane of the trans-dithiooxamide fragment due to steric hindrance and this effect is discussed.

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