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. 2002 Oct 21:(20):2432-3.
doi: 10.1039/b208325f.

Triple C-H activation of 1,5-bis(di-tert-butylphosphino)-2-(S)-dimethylaminopentane on ruthenium gives a chiral carbene complex

Vladimir F Kuznetsov  1 , Alan J Lough, Dmitry G Gusev
Affiliations

Triple C-H activation of 1,5-bis(di-tert-butylphosphino)-2-(S)-dimethylaminopentane on ruthenium gives a chiral carbene complex

Vladimir F Kuznetsov et al. Chem Commun (Camb). .

Abstract

This communication reports the preparation of a novel trans-chelating diphosphine, 1,5-bis(di-tert-butylphosphino)-2-(S)-dimethylaminopentane, that undergoes triple C-H activation in reaction with [RuCl2(p-cymene)]2 to give a chiral square-pyramidal 16-electron carbene complex of ruthenium.

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