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. 2002 Jun-Jul;21(6-7):427-33.
doi: 10.1081/NCN-120014815.

Formation of 2'-deoxy-2-nitroadenosines by reaction of 2'-deoxyadenosines with copper(II) nitrate/acetic anhydride

Toyo Kaiya  1 , Haruko Tanaka, Kohfuku Kohda
Affiliations

Formation of 2'-deoxy-2-nitroadenosines by reaction of 2'-deoxyadenosines with copper(II) nitrate/acetic anhydride

Toyo Kaiya et al. Nucleosides Nucleotides Nucleic Acids. 2002 Jun-Jul.

Abstract

Nitration of 9-substituted [ethyl, (Ac)2-2'-deoxyribosyl, (Ac)3-ribosyl] N6-acetyladenine derivatives with Cu(NO3)2.3H2O/Ac2O was examined. Nitration proceeded at the 2-position, although the yield was low. Removal of the acetyl groups gave 2'-deoxy-2-nitroadenosine derivatives.

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