Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2002 Oct;37(10):1007-12.
doi: 10.1007/s11745-006-0993-0.

Ozonation of PC in ethanol: separation and identification of a novel ethoxyhydroperoxide

Misako Tagiri-Endo  1 , Kaori Ono, Kiyotaka Nakagawa, Mari Yotsu-Yamashita, Teruo Miyazawa
Affiliations

Ozonation of PC in ethanol: separation and identification of a novel ethoxyhydroperoxide

Misako Tagiri-Endo et al. Lipids. 2002 Oct.

Abstract

The product of the ozonolysis of 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine in ethanol-containing solvent was analyzed by chemiluminescence detection-HPLC with on-line electrospray MS, and characterized on the basis of NMR spectroscopy and MS in high-resolution fast atom bombardment mode. The reaction yielded a large amount of a novel ethoxyhydroperoxide compound [1-palmitoyl-2-(9-ethoxy-9-hydroperoxynonanoyl)-sn-glycero-3-phosphcholinel. In addition to a structural analysis, we speculate on the reaction pathway and discuss the possibility of ethoxyhydroperoxide as a potentially reactive ozonized lipid in food and biological materials.

PubMed Disclaimer

References

    1. Am Rev Respir Dis. 1987 May;135(5):1124-8 - PubMed
    1. Anal Biochem. 1976 Nov;76(l):184-91 - PubMed
    1. Lipids. 1995 Nov;30(11):1001-6 - PubMed
    1. Lipids. 1992 Apr;27(4):289-94 - PubMed
    1. Anal Chem. 1996 Sep 15;68(18):3224-30 - PubMed

MeSH terms

LinkOut - more resources