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. 2002 Dec 21:(24):3044-5.
doi: 10.1039/b209486j.

A novel dicationic phenoxaphosphino-modified xantphos-type ligand--a unique ligand specifically designed for a high activity, selectivity and recyclability

Raymond P J Bronger  1 , Silvana M Silva, Paul C J Kamer, Piet W N M van Leeuwen
Affiliations

A novel dicationic phenoxaphosphino-modified xantphos-type ligand--a unique ligand specifically designed for a high activity, selectivity and recyclability

Raymond P J Bronger et al. Chem Commun (Camb). .

Abstract

A novel phenoxaphosphino-modified ligand has been prepared and successfully employed in the rhodium catalysed hydroformylation of 1-octene in ionic liquids showing unprecedented high selectivity and activity without detectable rhodium or phosphorus leaching during recycling experiments.

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