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. 2003 Feb 7:(3):410-1.
doi: 10.1039/b211395n.

Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized product

Todd C Harrop  1 , Marilyn M Olmstead, Pradip K Mascharak
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Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized product

Todd C Harrop et al. Chem Commun (Camb). .

Abstract

A (mu-SR)2-nickel(II) dimer derived from a ligand with carboxamido nitrogen and thiolato sulfur donors reacts with O2 to afford an oxidized product in which phenyl groups of the ligand frames are oxidized to nickel-bound phenolates.

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